
The fact that it clumps up is a good thing, this means that it's starting to dissolve: it just isn't going to finish anytime soon. Here's some things to try.
1) Add more solvent. One gram should, eventually, dissolve in 200mL (6.75 fl oz.) of water. You might try using 300mL. Don't worry about making your solution too dilute, you can always boil off excess solvent when you are done.
2) Mix it up. Break up the clumps with a pin; solubility increases with surface area. The more spread out you can get the powder, the greater it's chances of dissolving it will be.
3) Heat it up. Solubility also increases with temperature. The hotter you get it, the greater your chances of getting it to dissolve will be. When heating a substance you can also "supersaturate" the solution. When it is really hot, you can squeeze more milligrams of Yohimbe HCl
I hope this helps.